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 Form 4 Electrochemistry Topical Questions and Answers

The set-up below was used by a student to investigate the products formed when aqueous copper (II) chloride was electrolyzed using carbon electrodes.
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(a) (i) Write the equation for the reaction that takes place at the cathode.
(ii) Name and describe a chemical test for the product initially formed at the anode when a highly concentrated
solution of copper (II) chloride is electrolyzed.
(iii) How would the mass of the anode change if the carbon anode was replaced with copper metal? Explain.
(b) 0.6 g of metal B Were deposited when a current of O.45A was passed through an electrolyte for 72 minutes. Determine the charge on the ion of metal B. (Relative atomic mass of B = 59, 1 Faraday = 96 500 coulombs)
(c) The electrode potentials for cadmium and zinc are given below:
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Explain why it is not advisable to store a solution of cadmium nitrate in a container made of zinc.

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